REDOX-DEMERCURATION OF PHENYLMERCURY 4-FLUOROTHIOPHENOXIDE BY TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0)

DOI: 10.1016/0022-328X(85)80253-9

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C4 (1985)

Update date:2022-07-30

Topics: NMR spectra Chemical shifts Melting points Reaction Mechanism Byproducts

Authors:

Pombrik, S. I.

Bezrukova, A. A.

Golovchenko, L. S.

Peregudov, A. S.

Rubezhov, A. Z.

Kravtsov, D. N.

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Article abstract of DOI:10.1016/0022-328X(85)80253-9

A method for the synthesis of organoplatinum compounds containing a Pt-S ?-bond has been found.PhPt(PPh3)2SC6H4F-4 and 4-FC6H4Pt(PPh3)2SPh was obtained by redox-demercuration of PhHgSC6H4F-4 under the action of Pt(PPh3)4.

Full text of DOI:10.1016/0022-328X(85)80253-9

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Product name:trans-4-fluorophenylbis(triphenylphosphine)platinum chloride

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