85829-79-4Relevant academic research and scientific papers
α-Selective C(sp3)-H Thio/Selenocyanation of Ketones with Elemental Chalcogen
Li, Jin-Cheng,Gao, Wen-Xia,Liu, Miao-Chang,Zhou, Yun-Bing,Wu, Hua-Yue
, p. 17294 - 17306 (2021/12/02)
A facile method is disclosed for the synthesis of α-thio/selenocyanato ketones through regioselective C-H thio/selenocyanation of ketones. The advantages include the use of easily available starting materials, high efficiency, simple operation, and easy scale-up. Control experiments provide evidence that the reaction proceeded via a radical way, while kinetic isotope effect experiments reveal that the cleavage of the C-H bond serves as the rate-limiting step.
Thiazoline derivatives
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, (2008/06/13)
Heterocyclic compounds of the formula STR1 wherein A is a group STR2 and R1, R2, R3, R4, R5 and X are as defined hereinafter, process for their preparation, as well as pesticidal compositions containing one or more of these compounds as the active ingredient and methods for using the pesticidal compositions for the control of pests, particularly insects, mites and nematodes, are described.
2-Oxo-3 thiazoline-oximes as pesticides
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, (2008/06/13)
Carbamoyl-oximes of the formula STR1 wherein R1 and R3 each are lower alkyl, lower alkenyl, cycloalkyl, aryl or halogen-substituted aryl; R2 is lower alkyl; R4 is lower alkyl or cycloalkyl; and R5 is hydrogen, lower alkyl, lower alkylcarbonyl or halogen-substituted lower alkylcarbonyl, and acid addition salts of these compounds, a process for their preparation, pesticidal compositions containing one or more of these compounds as the active ingredient and methods for the use of such compositions for the control of pests.
