85829-79-4Relevant articles and documents
α-Selective C(sp3)-H Thio/Selenocyanation of Ketones with Elemental Chalcogen
Li, Jin-Cheng,Gao, Wen-Xia,Liu, Miao-Chang,Zhou, Yun-Bing,Wu, Hua-Yue
, p. 17294 - 17306 (2021/12/02)
A facile method is disclosed for the synthesis of α-thio/selenocyanato ketones through regioselective C-H thio/selenocyanation of ketones. The advantages include the use of easily available starting materials, high efficiency, simple operation, and easy scale-up. Control experiments provide evidence that the reaction proceeded via a radical way, while kinetic isotope effect experiments reveal that the cleavage of the C-H bond serves as the rate-limiting step.
2-Oxo-3 thiazoline-oximes as pesticides
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, (2008/06/13)
Carbamoyl-oximes of the formula STR1 wherein R1 and R3 each are lower alkyl, lower alkenyl, cycloalkyl, aryl or halogen-substituted aryl; R2 is lower alkyl; R4 is lower alkyl or cycloalkyl; and R5 is hydrogen, lower alkyl, lower alkylcarbonyl or halogen-substituted lower alkylcarbonyl, and acid addition salts of these compounds, a process for their preparation, pesticidal compositions containing one or more of these compounds as the active ingredient and methods for the use of such compositions for the control of pests.