85858-35-1Relevant articles and documents
Functionalisation of Saturated Hydrocarbons. Part 1. Some Reactions of a Ferrous Chloride-Chloramine-T Complex with Hydrocarbons
Barton, Derek H. R.,Hay-Motherwell, Robyn S.,Motherwell, William B.
, p. 445 - 452 (2007/10/02)
The reactions of several hydrocarbons substrates with a ferrous chloride-chloramine-T complex, generated in situ, have been studied.Tosylamination of adamantane and chlorination of mesitylene proceed in good yield while naphthalene gives N,N'-bis(toluene-p-sulphonyl)-1,4-naphthoquinone di-imine.A variety of olefinic substrates undergo both cis- and trans-addition to the double bond as well as allylic functionalisation.