85862-22-2Relevant academic research and scientific papers
Diazotization of pentafluoroaniline by means of anion-catalyzed phase transfer catalysis in a hydrophobic organic solvent
Iwamoto, Hidetoshi,Sonoda, Takaaki,Kobayashi, Hiroshi
, p. 535 - 537 (2007/10/02)
Anion-catalyzed phase-transfer catalysis was successfully applied to diazotization of pentafluoroaniline in a dichloromethane-aqueous sulfuric acid two-phase system.The resulting diazonium group was coupled in situ with anisole, 1-methoxynaphthalene, and mesitylene, and replaced in situ with bromo, hydryl, and phenyl substituents under a two-phase condition.
PREPARATION AND PHOTOCHEMICAL BEHAVIOUR OF 2,3,4,5,6-PENTAFLUOROPHENYLAZO-BENZENE AND -4'-METHOXYBENZENE
Crogan, Catherine,Fields, Roy,Pratt, Albert C.,Saleem, Layla M. N.,Dawson, Peter E.
, p. 61 - 72 (2007/10/02)
Pentafluoronitrosobenzene reacts readily with aniline and with p-methoxyaniline to give the corresponding 2,3,4,5,6-pentafluoroazobenzenes (1a and 1b) in good yield.Minor components detected by n.m.r. spectroscopy in the analitically pure products are sho
