85864-15-9

Upstream product

• 85864-13-7 [(E)-2-(3,3-Dimethoxy-propyl)-hexa-3,5-dienyloxymethyl]-benzene 
• 85864-12-6 (E)-2-(3,3-Dimethoxy-propyl)-hexa-3,5-dienoic acid methyl ester 
• 85864-11-5 (2E,4E)-2-(3,3-Dimethoxy-propyl)-hexa-2,4-dienoic acid methyl ester 
• 87101-66-4 (E)-2-(3,3-Dimethoxy-propyl)-hexa-3,5-dien-1-ol 
• 689-89-4 (2E,4E)-methylhexa-2,4-dienoate 
• 85864-14-8 (5E)-4-benzyloxymethyl-5,7-octadienal 

Downstream Products

• 85864-17-1 Acetic acid ((E)-4-benzyloxymethyl-octa-5,7-dienoylamino)-methyl ester 
• 85863-92-9 (1S,9aR)-1-Benzyloxymethyl-1,2,3,6,7,9a-hexahydro-quinolizin-4-one 
• 85864-16-0 (E)-4-Benzyloxymethyl-octa-5,7-dienoic acid amide 

Relevant academic research and scientific papers

A STEREOSELECTIVE TOTAL SYNTHESIS OF EPI-LUPININE

An intramolecular imino Diels-Alder reaction has been used both to construct the quinolizidine ring system and to set the proper relative stereochemistry of the alkaloid epi-lupinine (1).

Quinolizidine Alkaloid Synthesis via the Intramolecular Imino Diels-Alder Reaction. epi-Lupinine and Cryptopleurine

A totally stereoselective total synthesis of epi-lupinine (1) has been developed that starts with methyl sorbate (6).Alkylation of 6 with bromide 8 gave diene 10, which was elaborated into the imino Diels-Alder precursor 17.Thermolysis of 17 provided excl