85891-82-3

Basic information

• Product Name: 2-(phenylmethoxy)-α-methylstyrene
• Synonyms: 2-(phenylmethoxy)-α-methylstyrene
• CAS NO: 85891-82-3
• Molecular Weight: 224.302
• Mol File: 85891-82-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(phenylmethoxy)-α-methylstyrene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(phenylmethoxy)-α-methylstyrene(85891-82-3)
• EPA Substance Registry System: 2-(phenylmethoxy)-α-methylstyrene(85891-82-3)

Safety Data

• Hazardous Substances Data: 85891-82-3(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 31165-67-0 2'-benzyloxyacetophenone 
• 87307-75-3 2-(2-Benzyloxy-phenyl)-propan-2-ol 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 620-05-3 iodomethylbenzene 
• 118-93-4 o-hydroxyacetophenone 

Downstream Products

• 645405-50-1 2-(2-(benzyloxy)phenyl)propanal 
• 1424343-21-4 2-(2-benzyloxyphenyl)prop-2-en-1-ol 
• 85891-85-6 (E)-3-[4-(2-Benzyloxy-phenyl)-pyridin-3-yl]-acrylic acid ethyl ester 
• 85891-85-6 ethyl 3-<4-<2-(phenylmethoxy)phenyl>pyridin-3-yl>propenoate 
• 85891-86-7 ethyl 3-<4-(2-hydroxyphenyl)pyridin-3-yl>propanoate 
• 85891-87-8 4-<2-(2-ethoxy-2-oxoethoxy)phenyl>-1-methyl-3-(3-oxo-3-ethoxypropyl)pyridinium iodide 
• 87307-94-6 4-(2-hydroxyphenyl)-1-methyl-3-(3-oxo-3-ethoxypropyl)pyridinium iodide 
• 87307-76-4 ethyl 3-<4-<2-(phenylmethoxy)phenyl>pyridin-3-yl>propanoate 
• 85891-84-5 4-<2-(phenylmethoxy)phenyl>pyridine-3-carboxaldehyde 

Relevant articles and documents

Unexpected extension of usage of PPh3/CBr4, a versatile reagent: Isomerization of aromatic allylic alcohols

The PPh3/CBr4-catalyzed isomerization of 2-aromatic allylic alcohols into the corresponding saturated aldehydes or ketones has been achieved at room temperature in good to excellent yields under mild and metal-free conditions. This new methodology has been applied successfully to the synthesis of ibuprofen in four steps.

SYNTHESIS OF 3-METHYL-2,3,4,4a,5,6-HEXAHYDRO-1H-BENZOFUROISOQUINOLINE-7(7aH)-ONES

The 2,3,4,4a,5,6-hexahydro-1H-benzofuroisoquinoline-7(7aH)-one ring system is prepared from a 4-arylpyridine precursor by sequential intramolecular enolate addition to a pyridinium ion, Dieckmann cyclization, and catalytic hydrogenation.