85894-85-5

Upstream product

• 76605-82-8 6-methyl-cyclohex-1-en-1-yl trifluoromethanesulfonate 
• 882-33-7 diphenyldisulfane 
• 108-98-5 thiophenol 
• 108-94-1 cyclohexanone 
• 583-60-8 2-Methylcyclohexanone 
• 37457-08-2 cyclohexane-1,1-diylbis(phenylsulfane) 
• 7570-93-6 2-methyl-1-(phenylthio)cyclohexane 
• 85895-41-6 1,1-bis(phenylthio)-2-methylcyclohexane 
• 96227-44-0 2-methyl-1-(phenylsulfinyl)cyclohexane 
• 502-42-1 cycloheptanone 
• 502-49-8 cycloactanone 
• 4551-15-9 phenylthiotrimethylsilane 
• 19980-33-7 6-methyl-1-trimethylsiloxycyclohex-1-ene 
• 4922-47-8 1-(phenylthio)cyclohex-1-ene 

Downstream Products

• 128803-25-8 Cyclohexyl-(6-methyl-cyclohex-1-enyl)-methanol 
• 63883-85-2 1-lithio-6-methylcyclohexen 

Relevant academic research and scientific papers

Ruthenium-catalyzed reaction of alkenyl triflates with zinc thiolates

A ruthenium complex coordinated with 3,4,7,8-tetramethyl-1,10- phenanthroline catalyzed the reaction of alkenyl triflates with zinc dithiolates to give alkenyl sulfides.

THIOSILANES BASED DELIVERY OF SULFUR FUNCTIONALITIES IN ORGANIC SYNTHESIS

Thiosilanes have been proved efficient reagents in the transfer of sulfur functionalities onto organic substrates.

A Simple Method for Producing Cycloalkenyllithiums from Cycloalkanones via Reductive Lithiation of Enol Phenyl Thioethers

Cyclohexenyl, cycloheptenyl, and cyclooctenyl phenyl sulfides, readily prepared from the corresponding cycloalkanones, are reductively lithiated by lithium p,p'-di-tert-butylbiphenylide to produce cycloalkenyllithiums in good yields.

Clay Catalysis: A Simple and Efficient Synthesis of Enolthioethers from Cyclic Ketones

Montmorillonite KSF in refluxing toluene catalyses the synthesis of 1-alkyl- and 1-arylthioalkenes from ketones and thiols (thiophenol or 1-butanethiol).

ENOL THIOETHERS AS ENOL SUBSTITUTES. AN ALKYLATION SEQUENCE.

Ionic bromination of enol phenyl thiolethers forms predominantly to exclusively 2-(phenylthio)-3-bromo-1-alkenes, an enolonium equivalent. The allylic bromide participates in displacements with stabilized and nonstabilized nucleophiles. The ability to hydrolyze the enol thioethers to their corresponding ketones equates this sequence to an equivalence of an enolonium ion. The versatility of the sulfur in selective introduction of allylic hydroxyl and amino groups as well as the ability to directly replace the sulfur substituent by hydrogen or alkyl imparts special significance to this approach. The sequence is highly regio-and chemoselective. Applications include the synthesis of lanceol and bisabolene and the introduction of steroid side chains.