76605-82-8

Basic information

• Product Name: 6-Methyl-1-cyclohexenyl triflate
• Synonyms: 6-Methyl-1-cyclohexenyl triflate
• CAS NO: 76605-82-8
• Molecular Formula: C₈H₁₁F₃O₃S
• Molecular Weight: 244.2313496
• Mol File: 76605-82-8.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 73-77 °C(Press: 0.1 Torr)
• Appearance: /
• Density: 1.36±0.1 g/cm3(Predicted)
• CAS DataBase Reference: 6-Methyl-1-cyclohexenyl triflate(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Methyl-1-cyclohexenyl triflate(76605-82-8)
• EPA Substance Registry System: 6-Methyl-1-cyclohexenyl triflate(76605-82-8)

Safety Data

• Hazardous Substances Data: 76605-82-8(Hazardous Substances Data)

Upstream product

• 583-60-8 2-Methylcyclohexanone 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 37595-74-7 N,N-phenylbistrifluoromethane-sulfonimide 

Downstream Products

• 82201-24-9 (6-Methyl-cyclohex-1-enyl)-diphenyl-phosphane 
• 1243201-43-5 C₁₆H₁₈O 
• 1243201-45-7 C₁₆H₁₇ClO 
• 1243201-46-8 C₁₇H₂₀O₂ 
• 92622-61-2 1-(6-methylcyclohex-1-en-1-yl)prop-2-en-1-one 
• 41437-90-5 3-methylcyclohexene-2-carboxaldehyde 
• 5726-56-7 6-methylcyclohex-1-ene-1-carboxylic acid 
• 133957-40-1 5-(6-Methylcyclohexen-1-yl)uridine 
• 96575-64-3 methyl (E)-3-(6-methylcyclohexenyl)acrylate 
• 41437-89-2 (E)-4-(6-methylcyclohexenyl)but-3-en-2-one 

Relevant articles and documents

Steric effects on deprotonative generation of cyclohexynes and 1,2-cyclohexadienes from cyclohexenyl triflates by magnesium amides

Steric effects on the deprotonative generation of cyclohexynes and 1,2-cyclohexadienes from cyclohexenyl triflates are described. A cyclohexenyl triflate, which is readily available from nonsubstituted cyclohexanone, was selectively converted to cyclohexy

Cyclic Alkenylsulfonyl Fluorides: Palladium-Catalyzed Synthesis and Functionalization of Compact Multifunctional Reagents

A series of low-molecular-weight, compact, and multifunctional cyclic alkenylsulfonyl fluorides were efficiently prepared from the corresponding alkenyl triflates. Palladium-catalyzed sulfur dioxide insertion using the surrogate reagent DABSO effects sulfinate formation, before trapping with an F electrophile delivers the sulfonyl fluorides. A broad range of functional groups are tolerated, and a correspondingly large collection of derivatization reactions are possible on the products, including substitution at sulfur, conjugate addition, and N-functionalization. Together, these attributes suggest that this method could find new applications in chemical biology.

Cobalt- and Nickel-Catalyzed Carboxylation of Alkenyl and Sterically Hindered Aryl Triflates Utilizing CO2

A highly efficient cobalt-catalyzed reductive carboxylation reaction of alkenyl trifluoromethanesulfonates (triflates) has been developed. By employing Mn powder as a reducing reagent under 1 atm pressure of CO2 at room temperature, diverse alkenyl triflates can be converted to the corresponding α,β-unsaturated carboxylic acids. Moreover, the carboxylation of sterically hindered aryl triflates proceeds smoothly in the presence of a nickel or cobalt catalyst.