85895-36-9Relevant articles and documents
Anodic gem-Difluorination of Dithioacetals
Yoshiyama, Tomonori,Fuchigami, Toshio
, p. 1995 - 1998 (1992)
Anodic desulfurization of dithioacetals of ketones in the presence of Et3N*3HF provided the corresponding gem-difluorocompounds while dithioacetals of aromatic and aliphatic aldehydes gave gem-difluorothioethers and monofluoro thioether, respectively.
A CONVENIENT SYNTHESIS OF VINYL SULFIDES
Rodriguez, Abimael D.,Nickon, Alex
, p. 4443 - 4448 (2007/10/02)
Dithioketals are converted in good yields to vinyl sulfides by action of diethylzinc and methylene iodide.The reaction has been successfully applied to dialkyl and diaryl dithioketals, to spirocyclic analogs, and to a dithioacetal.A monothioketal produced a vinyl ether (enol ether) with the same reagent.