85895-63-2

Upstream product

• 108-98-5 thiophenol 
• 98-53-3 4-tercbutyl-cyclohexanone 

Downstream Products

• 89657-01-2 trans-1-(phenylthio)-1-(trimethylsilyl)-4-tert-butylcyclohexane 
• 100-68-5 methyl-phenyl-thioether 
• 71624-75-4 (4-tert-Butyl-cyclohex-1-enylsulfanyl)-benzene 
• 3178-22-1 tert-butylcyclohexane 
• 101448-85-5 4-tert-butylcyclohexyl phenyl sulfide 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 89657-03-4 (4-tert-butylcyclohexylidene)cyclohexylmethane 
• 89657-02-3 (4-tert-Butyl-1-trimethylsilanyl-cyclohexyl)-cyclohexyl-methanol 
• 85895-45-0 6-bromo-4-tert-butyl-1-(phenylthio)cyclohex-1-ene 
• 85895-46-1 2-bromo-1-(phenylthio)-4-tert-butylcyclohex-1-ene 
• 85894-99-1 dimethyl (2-(phenylthio)-5-tert-butyl-1-cyclohex-3-yl)malonate 
• 115663-65-5 1,1-bis(ethylthio)-4-tert-butylcyclohexane 

Relevant academic research and scientific papers

A Simple and Convenient Method for the Cleavage of Dithioacetals to the Corresponding Carbonyl Compounds

Carbonyl compounds were regenerated in high yields when corresponding diphenyl and diethyl dithioacetals were treated with a mixture of m-chloroperoxybenzoic acid/trifluoroacetic acid in dichloromethane.

A General Procedure for Preparing α-Lithiosilanes. Generalization of the Peterson Olefination

A particularly convenient method for the preparation of α-lithiosilanes consists of the reductive lithiation of diphenyl thioacetals or thioketals with lithium 1-(dimethylamino)naphthalenide, treatment of the resulting anion with trimethylsilyl chloride,

ENOL THIOETHERS AS ENOL SUBSTITUTES. AN ALKYLATION SEQUENCE.

Ionic bromination of enol phenyl thiolethers forms predominantly to exclusively 2-(phenylthio)-3-bromo-1-alkenes, an enolonium equivalent. The allylic bromide participates in displacements with stabilized and nonstabilized nucleophiles. The ability to hydrolyze the enol thioethers to their corresponding ketones equates this sequence to an equivalence of an enolonium ion. The versatility of the sulfur in selective introduction of allylic hydroxyl and amino groups as well as the ability to directly replace the sulfur substituent by hydrogen or alkyl imparts special significance to this approach. The sequence is highly regio-and chemoselective. Applications include the synthesis of lanceol and bisabolene and the introduction of steroid side chains.