71624-75-4

Basic information

• Product Name: (4-tert-Butyl-cyclohex-1-enylsulfanyl)-benzene
• Synonyms: (4-tert-Butyl-cyclohex-1-enylsulfanyl)-benzene
• CAS NO: 71624-75-4
• Molecular Weight: 246.417
• Mol File: 71624-75-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (4-tert-Butyl-cyclohex-1-enylsulfanyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (4-tert-Butyl-cyclohex-1-enylsulfanyl)-benzene(71624-75-4)
• EPA Substance Registry System: (4-tert-Butyl-cyclohex-1-enylsulfanyl)-benzene(71624-75-4)

Safety Data

• Hazardous Substances Data: 71624-75-4(Hazardous Substances Data)

Upstream product

• 119061-98-2 1-(tributylstannyl)-4-tert-butylcyclohexene 
• 63031-67-4 4-(1,1-dimethylethyl)cyclohexen-1-yltrimethylsilane 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 108-98-5 thiophenol 
• 930-69-8 sodium thiophenolate 
• 544-97-8 dimethyl zinc(II) 
• 85895-63-2 1,1-bis(phenylthio)-4-tert-butylcyclohexane 

Downstream Products

• 63031-67-4 4-(1,1-dimethylethyl)cyclohexen-1-yltrimethylsilane 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 85894-99-1 dimethyl (2-(phenylthio)-5-tert-butyl-1-cyclohex-3-yl)malonate 
• 151477-56-4 (4-tert-Butyl-cyclohex-1-enesulfonyl)-benzene 
• 102108-86-1 S-phenyl 4-tert-butyl-6-oxohexanethioate 
• 102108-87-2 (E)-5-tert-butyl-2-(phenylthio)cyclohexanone 
• 102108-87-2 (Z)-5-tert-butyl-2-(phenylthio)cyclohexanone 
• 85895-45-0 6-bromo-4-tert-butyl-1-(phenylthio)cyclohex-1-ene 
• 85895-46-1 2-bromo-1-(phenylthio)-4-tert-butylcyclohex-1-ene 

Relevant articles and documents

A Simple Method for Producing Cycloalkenyllithiums from Cycloalkanones via Reductive Lithiation of Enol Phenyl Thioethers

Cyclohexenyl, cycloheptenyl, and cyclooctenyl phenyl sulfides, readily prepared from the corresponding cycloalkanones, are reductively lithiated by lithium p,p'-di-tert-butylbiphenylide to produce cycloalkenyllithiums in good yields.

REACTIONS OF VINYLSILANES WITH LEWIS ACID-ACTIVATED IODOSYLBENZENE: STEREOSPECIFIC SYNTHESIS OF VINYLIODONIUM TETRAFLUOROBORATES AND THEIR REACTIONS AS HIGHLY ACTIVATED VINYL HALIDES

Alkenyl(phenyl)iodonium tetrafluoroborates 3 were synthesized from alkenylsilanes 1 by the reaction with iodosylbenzene and boron trifluoride-diethyl ether or triethyloxonium tetrafluoroborate.The reaction proceeds stereospecifically with retention of configuration of 1.X-ray diffraction analysis of (4-tert-butylcyclohexenyl)phenyliodonium tetrafluoroborate (3b) revealed the highly ionic structure with the distorted T-shape arrangement.Iodonium salts 3 behave like the highly activated species of vinyl iodides due to the high leaving ability of the iodine(III) substituents.Thus, a variety of substituted olefins including α-cyano and α-nitro olefins, vinyl sulfides, vinyl halides and α,β-unsaturated esters, were synthesized from 3 under mild conditions.A ligand coupling mechanism via the formation of 10-I-3 intermediate 27 containing a copper(III) ligand is proposed for the substitutions of 3 with nucleophiles.

VINYLIODONIUM SALTS: THEIR STEREOSPECIFIC SYNTHESIS AND REACTIONS AS THE ACTIVATED VINYL HALIDES

Vinyliodonium salts 2 were synthesized from vinylsilanes 1 by the reaction with iodosylbenzene and triethyloxonium tetrafluoroborate.The reaction occurs stereospecifically with retention of configuration.Vinyliodonium salts 2 are highly effective as the activated species of vinyl iodides.Thus, a variety of substituted olefins including α-cyano and α-nitro olefins, vinyl sulfides, vinyl halides, and α,β-unsaturated esters, were prepared from 2 under mild reaction conditions.