859499-49-3

Upstream product

• 108-86-1 bromobenzene 
• 177-11-7 4,4-ethylenedioxy-piperidine 
• 143-33-9 sodium cyanide 
• 198649-62-6 8-phenyl-1,4-dioxa-8-azaspiro[4,5]decane 

Downstream Products

• 859499-62-0 7-(3-chloropropyl)-8-phenyl-1,4-dioxa-8-azaspiro[4.5]decane-7-carbonitrile 
• 859499-51-7 7-(3-cyanopropyl)-8-phenyl-1,4-dioxa-8-azaspiro[4.5]decane-7-carbonitrile 
• 859499-52-8 4-(8-phenyl-1,4-dioxa-8-azaspiro[4.5]dec-7-yl)butanenitrile 
• 859499-53-9 4-(8-phenyl-1,4-dioxa-8-azaspiro[4.5]dec-7-yl)butanal 
• 859499-54-0 1-phenyl-2,3,6,7,8,8a-hexahydroquinolin-4(1H)-one 

Relevant academic research and scientific papers

Total synthesis of (±)-pumiliotoxin C: An electrochemical approach

The total stereoselective synthesis of the decahydroquinoline alkaloid (±)-pumiliotoxin C (cis-195A, 1) is described. The compound was prepared in 15 steps from the commercially available 4-piperidone ethylene ketal 2, in an overall 5% yield. New C-C bond