85972-81-2Relevant academic research and scientific papers
Cationic [(Iminophosphine)Nickel(Allyl)]+Complexes as the First Example of Nickel Catalysts for Direct Hydroamination of Allenes
Tafazolian, Hosein,Schmidt, Joseph A. R.
, p. 1507 - 1511 (2017)
The first example of nickel-catalyzed hydroamination of allenes is reported. The new cationic [(3-iminophosphine)nickel(allyl)]+catalysts have been fully characterized and act regioselectively in the catalytic hydroamination of allenes with sec
Electronic role of 3-iminophosphine ligands in palladium-catalyzed intermolecular hydroamination
Tafazolian, Hosein,Samblanet, Danielle C.,Schmidt, Joseph A.R.
, p. 1809 - 1817 (2015)
This study of the electronic characteristics of (3-iminophosphine)allylpalladium triflate complexes has yielded catalysts with moderate to high activity for the hydroamination of monosubstituted allenes utilizing a wide range of amines. Herein, a new seri
HYDROBORATION D'AMINES INSATUREES-II REGIO ET STEREOSELECTIVITE DE L'HYDROBORATION-ALKYLATION D'AMINES ACETYLENIQUES
Torregrosa, J. L.,Baboulene, M.,Speziale, V.,Lattes, A.
, p. 2355 - 2363 (2007/10/02)
The hydroboration reaction of acetylenic amines R1R2N-CH(R3)-CC-R4 was studied.We report the first results of a study of the reactivity of dialkylborane R2BH towards these amines which allow us to propose a new method for the synthesis of differently substituted β-ethylenic amines.The regioselectivity and the stereoselectivity of this reaction are examined and allow us to set out the possibility of a trans hydroboration.
