85995-67-1

Upstream product

• 110-83-8 cyclohexene 
• 1490-25-1 succinic acid monomethylester chloride 
• 51437-06-0 3-chloro-3-oxopropyl acetate 
• 107752-25-0 methyl 4-cyclohexenyl-4-nitrobutanoate 
• 1259476-03-3 C₁₁H₁₈O₄ 
• 7429-44-9 2-methoxycyclohexanone 

Downstream Products

• 2826-55-3 4-cyclohexylidenebutyric acid 
• 93085-67-7 4-cyclohex-1-enyl-4-semicarbazono-butyric acid methyl ester 
• 96232-73-4 4-(1'-Cyclohexenyl)-4-butanolide 

Relevant academic research and scientific papers

Geminal acylation of α-heterosubstituted cyclohexanones and their ketals

Geminal acylation of derivatives of cyclohexanone with Br, Cl, F, and OCH3 in the α position, and of their corresponding dimethyl ketals, could not be accomplished to a significant extent following published procedures. The transformation was a

Intermolecular cross-double-Michael addition between nitro and carbonyl activated olefins as a new approach in C-C bond formation

(Chemical Equation Presented) A novel intermolecular cross-double-Michael addition between nitro and carbonyl activated olefins has been developed through Lewis base catalysis. The reaction took place with a large group of β-alkyl nitroalkenes and α,β-uns

Novel Acylation of Aliphatic Olefins Promoted by Active Zinc Compounds

It was found that acylation of a variety of aliphatic olefins with acid chlorides is efficiently promoted by active zinc compounds, which were prepared from a Zn/Cu couple and alkyl iodides.The crude product mixtures were subsequently treated with 1 M KOH in methanol or were subjected to catalytic hydrogenation to afford the corresponding α,β-unsaturated or saturated ketones in good to moderate yields.It was also shown that the reaction fully follows the Markovnikov rule.