85997-36-0

Upstream product

• 102-01-2 N-phenylacetoacetamide 
• 540-63-6 ethane-1,2-dithiol 
• 135081-30-0 cis-2-methyl-N-phenyl-1,3-dithiolane-2-acetamide 1-oxide 
• 135081-30-0 trans-2-methyl-N-phenyl-1,3-dithiolane-2-acetamide 1-oxide 

Downstream Products

• 135081-30-0 cis-2-methyl-N-phenyl-1,3-dithiolane-2-acetamide 1-oxide 
• 135081-30-0 trans-2-methyl-N-phenyl-1,3-dithiolane-2-acetamide 1-oxide 
• 135081-33-3 (+/-)-2-methyl-N-phenyl-1,3-dithiolane-2-acetamide 1,3-dioxide 
• 138481-34-2 2-methyl-N-phenyl-1,3-dithiolane-2-acetamide 1,3-dioxide 
• 135081-33-3 2-(2-Methyl-1,3-dioxo-1λ⁴,3λ⁴-[1,3]dithiolan-2-yl)-N-phenyl-acetamide 
• 138481-35-3 2-methyl-N-phenyl-1,3-dithiolane-2-acetamide 1,3-dioxide 
• 138481-37-5 (E)-3-{2-[2-((E)-1-Methyl-2-phenylcarbamoyl-vinylsulfanyl)-ethyldisulfanyl]-ethylsulfanyl}-but-2-enoic acid phenylamide 
• 138481-43-3 C₁₂H₁₂⁽²⁾H₃NO₂S₂ 
• 138481-42-2 C₁₂H₁₃⁽²⁾H₂NO₂S₂ 
• 138481-37-5 (E)-3-{2-[2-((E)-1-Methyl-2-phenylcarbamoyl-vinylsulfanyl)-ethyldisulfanyl]-ethylsulfanyl}-but-2-enoic acid phenylamide 
• 35756-30-0 5,6-dihydro-2-methyl-1,4-dithiine-N-phenyl-3-carboxamide 
• 138481-36-4 2-(5,6-Dihydro-[1,4]dithiin-2-yl)-N-phenyl-acetamide 

Relevant academic research and scientific papers

REARRANGEMENT MECHANISMS OF SOME CYCLIC SULFOXIDES.

Under neutral conditions cis sulfoxides 5 underwent a sigmatropic rearrangement with 2-methylene hydrogens to give sulfenic acids 18, followed by cyclization to dihydro-1,4-dithiins 2.The trans sulfoxides 6 rearranged involving 2-methyl hydrogens to form

Rearrangement mechanisms of 1,3-dithiolane sulfoxides

Oxidation of sulfide 4 gave a mixture of cis and trans monosulfoxides 5 and 6 is as major and minor products, respectively, plus a small amount of disulfoxides 7. The structural assignments of cis and trans sulfoxides 5 and 6 were based on 1H N