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Triphenylphosphine(ethylisocyanide)dicarbonyldibromoiron(II) is a complex organometallic compound with the chemical formula C23H20Br2FeNO2P. It consists of a central iron(II) atom coordinated to two bromine atoms, two carbonyl groups, a triphenylphosphine ligand, and an ethylisocyanide ligand. triphenylphosphine(ethylisocyanide)dicarbonyldibromoiron(II) is of interest in organometallic chemistry and catalysis due to its unique structure and potential applications in various chemical transformations. The presence of the triphenylphosphine and ethylisocyanide ligands provides steric and electronic effects that can influence the reactivity and selectivity of the complex.

86015-62-5

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86015-62-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 86015-62-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,0,1 and 5 respectively; the second part has 2 digits, 6 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 86015-62:
(7*8)+(6*6)+(5*0)+(4*1)+(3*5)+(2*6)+(1*2)=125
125 % 10 = 5
So 86015-62-5 is a valid CAS Registry Number.

86015-62-5Downstream Products

86015-62-5Relevant academic research and scientific papers

Reductive Elimination and Substitution Reactions of Bis(triphenylphosphine)-dicarbonyldibromoiron(II)

Vancheesan, S.

, p. 54 - 55 (2007/10/02)

The title complex, Fe(CO)2(PPh3)2Br2(A) undergoes (i) substitution and (ii) reductive elimination.Substitution has been carried out with a variety of isocyanides, wherein a phosphine, a carbonyl or both the ligands are replaced by RNC.The extent and nature of the substitution varies with R, mol ratio of complex (A) to RNC and temperature.Reductive elimination has been carried out using Na/Hg as reducing agent in the presence of excess ligand L to get products of the type Fe(CO)2(PPh3)2L. ?-? character of L influence CO streaching frequencies.

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