86043-04-1

Basic information

• Product Name: 1-(4-(trifluoromethyl)phenyl)-2,3-dihydro-1H-indene
• Synonyms: 1-(4-(trifluoromethyl)phenyl)-2,3-dihydro-1H-indene
• CAS NO: 86043-04-1
• Molecular Weight: 262.274
• Mol File: 86043-04-1.mol

Chemical Properties

• CAS DataBase Reference: 1-(4-(trifluoromethyl)phenyl)-2,3-dihydro-1H-indene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-(trifluoromethyl)phenyl)-2,3-dihydro-1H-indene(86043-04-1)
• EPA Substance Registry System: 1-(4-(trifluoromethyl)phenyl)-2,3-dihydro-1H-indene(86043-04-1)

Safety Data

• Hazardous Substances Data: 86043-04-1(Hazardous Substances Data)

Upstream product

• 402-43-7 p-trifluoromethylphenyl bromide 
• 345-88-0 1-phenyl-1-(4-trifluoromethylphenyl)ethylene 
• 73424-46-1 N'-(2,3-dihydro-1H-inden-1-ylidene)-4-methylbenzenesulfonohydrazide 
• 128796-39-4 4-trifluoromethylphenylboronic acid 
• 83-33-0 inden-1-one 
• 113793-10-5 1-(p-(trifluoromethyl)phenyl)indanol 
• 113793-11-6 3-(4-(trifluoromethyl)phenyl)-1H-indene 
• 86042-98-0 1-phenyl-1-(p-(trifluoromethyl)phenyl)cyclopropane 

Relevant articles and documents

Synthesis of 1-aryl- benzocycloalkane derivatives via one-pot two-step reaction of benzocyclonone, tosylhydrazide, and arylboronic acid

A metal-free one-pot two-step reductive coupling reaction of benzocyclonone, tosylhydrazide, and arylboronic acid was developed for the formation of a C(sp3)–C(sp2) bond, which enabled the efficient synthesis of 1-aryl-benzocycloalkane compounds in moderate to good yields on a multi-gram scale. Moreover, five- and six-membered benzocyclic ketones are also suitable substrates for this reaction. Notably, this protocol was also found to be suitable for synthesizing 3-(3,4-dichlorophenyl)-2,3-dihydro-1H-inden-1-one, an important intermediate in the synthesis of indatraline.

Arylcyclopropane Photochemistry. Effects of Electron-Donating and Electron-Withdrawing Aromatic Substituents on the Photochemical Rearrangements of 1,1-Diarylcyclopropanes.

Irradiation of 1,1-diarylcyclopropanes 4a-g, having substituents X and Y at the para positions of the aromatic rings, afforded 1,1-diarylpropenes 5a-g and 1-arylindans 6a-f.The rate constants of these (singlet state) reactions, determined from the reactan

ARYLCYCLOPROPANE PHOTOCHEMISTRY. SUBSTITUENT EFFECTS ON THE PHOTOCHEMICAL CONVERSION OF 1,1-DIARYLCYCLOPROPANES TO 1,1-DIARYLPROPENES AND 1-ARYLINDANES.

The rate of photochemical rearrangement of 1,1-diarylcyclopropanes to 1,1-diarylpropenes and 1-arylindanes is enhanced by electron-withdrawing groups on the aromatic rings and diminished by electron-donating groups.