73424-46-1Relevant articles and documents
Indan-C60: From a crystalline molecule to photovoltaic application
Wang, Taishan,Liao, Xiaxia,Wang, Jizheng,Wang, Chunru,Chan, Mei-Yee,Yam, Vivian Wing-Wah
, p. 9923 - 9925 (2013)
Crystalline Indan-C60 and its photovoltaic application were studied. Microsheets and aloe-like micro-nano superstructures can be assembled from Indan-C60. Indan-PC61BM derived from Indan-C 60 was further investigated as an acceptor for OPV devices, which shows a higher Voc, FF, and PCE than those obtained using PC 61BM.
Synthesis of 1-aryl- benzocycloalkane derivatives via one-pot two-step reaction of benzocyclonone, tosylhydrazide, and arylboronic acid
Liu, Shijuan,Fang, Meitong,Yin, Dongni,Wang, Yanan,Liu, Lei,Li, Xiuying,Che, Guangbo
, p. 942 - 949 (2019/03/14)
A metal-free one-pot two-step reductive coupling reaction of benzocyclonone, tosylhydrazide, and arylboronic acid was developed for the formation of a C(sp3)–C(sp2) bond, which enabled the efficient synthesis of 1-aryl-benzocycloalkane compounds in moderate to good yields on a multi-gram scale. Moreover, five- and six-membered benzocyclic ketones are also suitable substrates for this reaction. Notably, this protocol was also found to be suitable for synthesizing 3-(3,4-dichlorophenyl)-2,3-dihydro-1H-inden-1-one, an important intermediate in the synthesis of indatraline.
Copper-Catalyzed Cyanation of N-Tosylhydrazones with Thiocyanate Salt as the "cN" Source
Huang, Yubing,Yu, Yue,Zhu, Zhongzhi,Zhu, Chuanle,Cen, Jinghe,Li, Xianwei,Wu, Wanqing,Jiang, Huanfeng
, p. 7621 - 7627 (2017/07/26)
A novel protocol for the synthesis of α-aryl nitriles has been successfully achieved via a copper-catalyzed cyanation of N-tosylhydrazones employing thiocyanate as the source of cyanide. The features of this method include a convenient operation, readily available substrates, low-toxicity thiocyanate salts, and a broad substrate scope.