86045-68-3

Upstream product

• 86045-78-5 4a-Ethyl-4-phenylsulfanyl-2,3,4,4a,5,6-hexahydro-1H-[1]pyrindine 
• 86045-77-4 2-Ethyl-2-(3-iodo-1-phenylsulfanyl-propyl)-cyclopentanone 
• 86045-65-0 2-ethyl-2-<3-chloro-1-(phenylthio)propyl>cyclopentanone 
• 52072-18-1 1,3-dichloro-1-(phenylthio)propane 
• 86045-66-1 4a-ethyl-1-(methoxycarbonyl)-4-(phenylthio)-2,3,4,4a,5,6-hexahydro-1H-1-pyrindine 

Downstream Products

• 86045-73-0 4aα-ethyl-7α-<1-(4-methoxy-2-aminophenyl)ethenyl>-2,4a,5,6,7,7aα-hexahydro-1H-1-pyrindin-7-ol 
• 86064-57-5 4aα-ethyl-7α-<1-<4-methoxy-2-(trimethylacetamido)-phenyl>ethenyl>-2,4a,5,6,7,7aα-hexahydro-1H-1-pyrindin-7-ol 
• 86045-72-9 6aα-ethyl-9aα-<4-methoxy-2-(trimethylacetamido)-phenyl>-1,2,4,6a,7,8,9a,9bα-octahydro-9H-pyrrolo<3,2,1-ij>quinolin-9-one 
• 86045-71-8 6aα-ethyl-8aα-<1-<4-methoxy-2-(trimethylacetamido)-phenyl>ethenyl>-1,2,4,6a,7,8,8a,8bα-octahydro-1-oxacyclopentindolizin-2-one 
• 86064-56-4 6aα-ethyl-8aα-<4-methoxy-2-(trimethylacetamido)-benzoyl>1,2,4,6a,7,8,8a,8bα-octahydro-1-oxacyclopentindolizin-2-one 

Relevant academic research and scientific papers

A New Approach for the Total Synthesis of Pentacyclic Aspidosperma Alkaloids. Total Synthesis of dl-16-Methoxytabersonine

The pentacyclic Aspidosperma alkaloid dl-16-methoxytabersonine (1) has been synthesized by an efficient convergent sequence.The key step in the synthesis is the "ring-enlarging pyrrolidine annulation" reaction of 7-styrylhydropyridin-7-ols 17 and 18 to gi