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86051-37-8

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86051-37-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 86051-37-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,0,5 and 1 respectively; the second part has 2 digits, 3 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 86051-37:
(7*8)+(6*6)+(5*0)+(4*5)+(3*1)+(2*3)+(1*7)=128
128 % 10 = 8
So 86051-37-8 is a valid CAS Registry Number.

86051-37-8Relevant articles and documents

Catalytic Asymmetric Hydroalkylation of α,β-Unsaturated Amides Enabled by Regio-Reversed and Enantiodifferentiating syn-Hydronickellation

Zhou, Fang,Zhu, Shaolin

, p. 8766 - 8773 (2021/07/26)

Here, we report an enantioselective nickel-hydride catalyzed hydroalkylation of readily accessible β-alkyl-α,β-unsaturated amides to form structurally diverse β-chiral amides. This process was proposed to proceed through an enantiodifferentiating syn-hydrometalation of nickel hydride, forming chiral alkylnickel at the β-position in which the regioselectivity is different from that with copper hydride. This regio-reversed hydronickellation process provides a complementary approach to access enantioenriched β-functionalization amides with a stereocenter at the β-position.

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