86051-60-7Relevant academic research and scientific papers
An unexpected silver triflate catalyzed reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate
Zheng, Danqing,Li, Shaoyu,Wu, Jie
supporting information; experimental part, p. 2655 - 2657 (2012/07/16)
An unexpected silver triflate catalyzed reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate provides an efficient route for the generation of isoquinolines. The reaction proceeds smoothly in air under mild conditions with high efficiency.
A tandem approach to isoquinolines from 2-azido-3-arylacrylates and α-diazocarbonyl compounds
Yang, Yun-Yun,Shou, Wang-Ge,Chen, Zheng-Bo,Hong, Deng,Wang, Yan-Guang
, p. 3928 - 3930 (2008/09/19)
(Chemical Equation Presented) 2-Azido-3-arylacrylates react with α-diazocarbonyl compounds and triphenylphosphine to furnish isoquinolines in 60-92% yields. The tandem process involves a Wolff rearrangement, an aza-Wittig reaction, and an electrocyclic ri
Vinyl Azides in Heterocyclic Synthesis. Part 2. Selectivity in the Decomposition of Azidocinnamates with Olefinic ortho-Substituents
Hickey, Deirdre M. B.,Moody, Christopher J.,Rees, Charles W.
, p. 1113 - 1118 (2007/10/02)
Thermolysis of azidocinnamates with an olefinic o-substituent gives products (isoquinolines, azepines, aziridines) formed by selective interaction of the azide, and the derived nitrene, with the olefinic substituent, cyclisation onto the unsubstituted aro
Selectivity in Vinyl Azide Reactions; Decomposition of Azidocinnamates with Olefinic ortho-Substituents
Hickey, Deirdre M. B.,Moody, Christopher J.,Rees, Charles W.
, p. 1419 - 1421 (2007/10/02)
Thermal decomposition of vinyl azides (1a - c) gives isoquinolines (3), benzazepines (4), or aziridines (5) and (6) by preferential reaction at the unsaturated substituent; removal of this unsaturation as in the epoxides (1d, 1e) leads exclusively to 4-substituted indoles.
