860577-22-6

Basic information

• Product Name: acylaminophenylallylsulfide
• Synonyms: acylaminophenylallylsulfide
• CAS NO: 860577-22-6
• Molecular Weight: 207.296
• Mol File: 860577-22-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: acylaminophenylallylsulfide(CAS DataBase Reference)
• NIST Chemistry Reference: acylaminophenylallylsulfide(860577-22-6)
• EPA Substance Registry System: acylaminophenylallylsulfide(860577-22-6)

Safety Data

• Hazardous Substances Data: 860577-22-6(Hazardous Substances Data)

Upstream product

• 106-95-6 allyl bromide 
• 1126-81-4 4-acetamidothiophenol 
• 32894-70-5 allyl 4-nitrophenyl sulfide 
• 19284-79-8 4-(allylthio)aniline 
• 108-24-7 acetic anhydride 

Downstream Products

• 1415703-89-7 N-(4-((2,2,2-trifluoroethyl)thio)phenyl) acetamide 

Relevant articles and documents

Hemin Catalyzed Dealkylative Intercepted [2, 3]-Sigmatropic Rearrangement Reactions of Sulfonium Ylides with 2, 2, 2-Trifluorodiazoethane

A dealkylative intercepted [2, 3]-sigmatropic rearrangement reaction of allylic sulfides with 2, 2, 2-trifluorodiazoethane (CF3CHN2) is reported, the commercially available and biocompatible catalyst hemin was found to efficiently catalyze this transformation across a diverse set of allylic sulfides with in situ generated CF3CHN2, providing excellent yields (up to 99%) under mild condition without inert gas protection. In addition, CF3CHN2 exhibited unique reactivity toward this process compared with other frequently used diazo reagents. This work expands the range of carbene-mediated transformations catalyzed by hemin and introduces a concise and general strategy for exploiting new possibility of reactions concerning organosulfides. (Figure presented.).