32894-70-5

Basic information

• Product Name: 1-nitro-4-(prop-2-en-1-ylsulfanyl)benzene
• CAS NO: 32894-70-5
• Molecular Formula: C₉H₉NO₂S
• Molecular Weight: 195.2383
• Mol File: 32894-70-5.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 302.6°C at 760 mmHg
• Flash Point: 136.8°C
• Density: 1.21g/cm³
• Vapor Pressure: 0.00176mmHg at 25°C
• Refractive Index: 1.593
• CAS DataBase Reference: 1-nitro-4-(prop-2-en-1-ylsulfanyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-nitro-4-(prop-2-en-1-ylsulfanyl)benzene(32894-70-5)
• EPA Substance Registry System: 1-nitro-4-(prop-2-en-1-ylsulfanyl)benzene(32894-70-5)

Safety Data

• Hazardous Substances Data: 32894-70-5(Hazardous Substances Data)

Usage

Nitro compound

A chemical compound containing a nitro group (-NO2), which is a functional group consisting of an oxygen-nitrogen-oxygen bond.

Benzene ring

A six-membered aromatic ring structure with alternating single and double carbon-carbon bonds, which is a fundamental structural motif in organic chemistry.

Substituted with a nitro group

The nitro group (-NO2) is attached to one of the carbon atoms on the benzene ring, which modifies the chemical properties of the benzene ring.

Prop-2-en-1-ylsulfanyl group

A functional group consisting of a sulfur atom bound to a prop-2-en-1-yl (or allyl) group, which is a common structural motif in organic chemistry.

Common use in synthesis

1-nitro-4-(prop-2-en-1-ylsulfanyl)benzene is often used as a starting material or intermediate in the synthesis of various organic compounds.

Health and safety risks

Proper handling and management of 1-nitro-4-(prop-2-en-1-ylsulfanyl)benzene is crucial, as it can pose potential hazards to human health and the environment if not handled correctly.

Upstream product

• 106-95-6 allyl bromide 
• 824-78-2 4-nitrophenol sodium salt 
• 591-96-8 penta-2,3-diene 
• 130436-13-4 C₁₂H₁₅NO₃S 
• 598-25-4 Dimethylallene 
• 1849-36-1 para-nitrobenzenethiol 
• 81650-42-2 3-(p-nitrophenylsulfinyl)prop-1-ene 
• 161941-53-3 4,5-Epoxy-2-methyl-2-pentyl 4-nitrobenzenesulfenate 
• 100-00-5 4-chlorobenzonitrile 
• 130436-12-3 C₁₁H₁₃NO₃S 
• 130436-11-2 C₁₀H₁₁NO₃S 
• 107-05-1 3-chloroprop-1-ene 
• 937-32-6 4-nitrobenzenesulfenyl chloride 
• 100-32-3 di(p-nitrophenyl) disulfide 

Downstream Products

• 112-88-9 octadec-1-ene 
• 89025-53-6 n-pentadecyl-2'-pyridylsulphide 
• 860577-22-6 acylaminophenylallylsulfide 
• 78020-99-2 2,4-diphenyl-6-(p-nitrophenylsulfinylmethyl)-1,3-dioxan 
• 78012-61-0 (E)-1-phenyl-4-(p-nitrophenylsulfinyl)but-3-en-1-ol 
• 81650-42-2 3-(p-nitrophenylsulfinyl)prop-1-ene 
• 113943-91-2 cis-3-(4-chlorophenyl)-3-<(1H-imidazol-1-yl)methyl>-2-methyl-5-<<(4-nitrophenyl)thio>methyl>isoxazolidine 

Relevant articles and documents

Ruthenium-catalyzed decarboxylative C-S cross-coupling of carbonothioate: synthesis of allyl(aryl)sulfide

A novel ruthenium-catalyzed decarboxylative cross-coupling of carbonothioate is disclosed. This method provides straightforward access to the corresponding allyl(aryl)sulfide derivatives in generally good to excellent yields under mild conditions and feat

Nickel-Schiff base complex catalyzed C-S cross-coupling of thiols with organic chlorides

We report an efficient, mild and convenient synthetic protocol for the C-S cross-coupling reaction of various aryl, benzyl, allyl chlorides and thiols using 5 mol % Nickel-Schiff base catalyst with NaOH as the base, in DMF at 70 °C. Using this protocol, we have shown that a variety of aryl sulfides can be synthesized in excellent yields from readily available organic chlorides and thiols.

Sulfite-promoted one-pot synthesis of sulfides by reaction of aryl disulfides with alkyl halides

A sodium dithionite, sodium thiosulfate and rongalite promoted one-pot synthesis of aryl alkyl sulfides at room temperature has been developed. The reactions of a range of disulfides with alkyl halides proceeded smoothly in the presence of rongalite. Possible reaction pathways are discussed and the effects of these sulfites on disulfides are investigated. The important features of this protocol are metal-free, strong-base-free, and mild reaction conditions, operational simplicity, short reaction times and high yields of products. Georg Thieme Verlag Stuttgart.