860624-20-0

Basic information

• Product Name: 6-chloro-5-methoxy-3-oxo-hexanoic acid benzyl ester
• Synonyms: 6-chloro-5-methoxy-3-oxo-hexanoic acid benzyl ester
• CAS NO: 860624-20-0
• Molecular Weight: 284.74
• Mol File: 860624-20-0.mol

Chemical Properties

• CAS DataBase Reference: 6-chloro-5-methoxy-3-oxo-hexanoic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 6-chloro-5-methoxy-3-oxo-hexanoic acid benzyl ester(860624-20-0)
• EPA Substance Registry System: 6-chloro-5-methoxy-3-oxo-hexanoic acid benzyl ester(860624-20-0)

Safety Data

• Hazardous Substances Data: 860624-20-0(Hazardous Substances Data)

Upstream product

• 97-97-2 chloroacetaldehyde dimethyl acetal 

Relevant articles and documents

Regioselective synthesis of functionalized furans by cyclization of 1,3-bis-silyl enol ethers with 1-chloro-2,2-dimethoxyethane

Cyclization of 1,3-bis-silyl enol ethers with 1-chloro-2,2-dimethoxyethane allowed an efficient, regio- and diastereo-selective synthesis of a variety of 2-alkylidene-4-methoxy-tetrahydrofurans. The TFA-mediated elimination of methanol resulted in the formation of functionalized furans. Simi larly, 2,3,3a,4,5,6-hexahydro-2,3-benzofurans were prepared and transformed into 4,5,6,7-tetrahydro-2,3-benzofurans by treatment with TFA Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.

Chemo-, regio-, and stereoselective cyclizations of 1,3-bis(trimethylsilyloxy)-1,3-butadienes with α-chloroacetic acid chlorides and α-chloroacetic acetals

Treatment of 1,3-bis(trimethylsilyloxy)-1,3-butadienes with α-chlorocarboxylic acid chlorides resulted in chemo- and regioselective formation of 6-chloro-3,5-dioxo esters, which were regioselectively converted into functionalised 3(2H)furanones. Chemo- an