860774-45-4

Upstream product

• 13163-77-4 1-phenylhept-6-ene-1,3-dione 
• 99564-80-4 (Z)-1-phenyl-1,3-bis(trimethylsilyloxy)-1,3-butadiene 
• 75-56-9 methyloxirane 
• 78994-36-2 (2Z)-3-(butylamino)-1-phenylbut-2-en-1-one 
• 144174-97-0 3-(N-Butylamino)-6-hydroxy-1-phenylhept-2-en-1-one 

Relevant academic research and scientific papers

Synthesis of 4-(3-hydroxyalkyl)pyrimidines by ring transformation reactions of 2-alkylidenetetrahydrofurans with amidines

Domino reactions of amidines with 2-alkylidenetetrahydrofurans, prepared by cyclization of 1,3-dicarbonyl dianions or 1,3-bis-silyl enol ethers with various dielectrophiles, provided an efficient access to 4-(3-hydroxyalkyl)pyrimidines.

Highly efficient, reversible addition of activated methylene compounds to styrene derivatives catalyzed by silver catalysts

A highly efficient inter- and intramolecular addition of 1,3-diketone/β-ketoester to alkenes was developed by using silver catalysts. Silver triflate shows the highest catalytic activity. The reaction is reversible through the cleavage of a carbon-carbon bond by silver at an elevated temperature.

Reaction of Dianions of Acyclic β-Enamino Ketones with Electrophiles. Part 2. Oxiranes: Synthesis of γ'- and ε-Hydroxy-β-enamino Ketones and of α-Tetrahydrofurylidene Ketones.

β-Monoalkylamino-α,β-unsaturated ketones can be regioselectively dimetallated either at the α'- or in the γ-positions.The reaction of the resulting dianions with oxiranes proceeds in good to high yields affording the corresponding hydroxyalkyl derivatives