860776-15-4Relevant academic research and scientific papers
Oxidative coupling of methoxynaphthylenediols
Maiti, Bhim C.,Musgrave, Oliver C.,Skoyles, Douglas
, p. 6568 - 6574 (2007/10/03)
The oxidative coupling of a mixture of 1-methoxy-7-methyl-4,5- naphthylenediol and 4-methoxy-7-methyl-1,5-naphthylenediol using lead(IV) oxide gives the symmetrical bisnaphthalene indigos diosindigo A and diosindigo B together with the corresponding unsymmetrical isomer. Oxidation of the first two by nitric acid gives the binaphthyldiquinones mamegakinone and biramentaceone, respectively; the third gives the unsymmetrical diquinone rotundiquinone. Similar oxidations of related naphthylenediols are described.
