861109-16-2Relevant academic research and scientific papers
Lewis acid mediated asymmetric [2,3]-sigmatropic rearrangement of allylic amines. Scope and mechanistic investigation
Blid, Jan,Panknin, Olaf,Tuzina, Pavel,Somfai, Peter
, p. 1294 - 1300 (2007/10/03)
(Chemical Equation Presented) The first asymmetric [2,3]-sigmatropic rearrangement of achiral allylic amines has been realized by quaternization of the amines with an enantiomerically pure diazaborolidine and subsequent treatment with Et3N. The
