861144-46-9

Upstream product

• 105-13-5 4-Methoxybenzyl alcohol 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 861144-55-0 (R)-2-Methyl-3-methylene-1,1-dipropoxy-pentan-2-ol 
• 861144-47-0 (S)-2-Hydroxy-2-methyl-1,1-dipropoxy-pentan-3-one 
• 861144-48-1 1-((R)-1-Dipropoxymethyl-1-methyl-2-methylene-butoxymethyl)-4-methoxy-benzene 

Downstream Products

• 861144-50-5 (Z)-(S)-2-Acetyl-4-(4-methoxy-benzyloxy)-4-methyl-5-oxo-hept-2-enoic acid ethyl ester 
• 861144-43-6 (S)-4-((2E,4E)-Hexa-2,4-dienoyl)-3-hydroxy-6-(4-methoxy-benzyloxy)-2,6-dimethyl-cyclohexa-2,4-dienone 
• 861144-54-9 (4E,6E)-2-[(S)-2-(4-Methoxy-benzyloxy)-2-methyl-3-oxo-pent-(Z)-ylidene]-3-oxo-octa-4,6-dienoic acid ethyl ester 
• 861144-49-2 (Z)-(S)-2-Acetyl-4-(4-methoxy-benzyloxy)-4-methyl-5-methylene-hept-2-enoic acid ethyl ester 
• 861144-52-7 2-[(S)-2-(4-Methoxy-benzyloxy)-2-methyl-3-methylene-pent-(Z)-ylidene]-3-oxo-oct-4-ynoic acid ethyl ester 

Relevant academic research and scientific papers

Catalytic enantioselective total syntheses of bisorbicillinolide, bisorbicillinol, and bisorbibutenolide

(Chemical Equation Presented) A modified cinchona alkaloid catalyzed ketone cyanosilylation reaction is used as the stereochemistry-defining step in the total synthesis of sorbicillinol derivatives (a protected derivative is shown (PMB = para-methoxybenzy