861377-84-6Relevant academic research and scientific papers
C-N Bond Activation of N, N′-Dialkylacylhydrazines Mediated by β-Fragmentation of Nitrogen-Centered Radical
Zhang, Yuxian,Zhang, Shuwei,Sun, Zheng,He, Kaixuan,Chen, Qian,Yuan, Yu,Jia, Xiaodong
, p. 14202 - 14208 (2019/10/16)
In the presence of tert-butylnitrite and dioxygen, the C-N bond activation of N,N′-dialkylacylhydrazines was realized, providing a series of N-nitrosoacylhydrazines in high yields. Different from transition-metal and other radical catalysis, this reaction is mediated by a nitrogen-centered radical of the corresponding N,N′-dialkylacylhydrazine and further β-fragmentation, which was supported by the mechanistic study.
