86145-10-0Relevant academic research and scientific papers
A NEW APPROACH TO ARYLMALONONITRILES
Yamaguchi, Shunro,Araki, Hisashi,Hanafusa, Terukiyo
, p. 685 - 688 (1985)
Arylmalononitriles were prepared from the corresponding benzoyl chlorides by three reaction steps.Treatment of the starting substances with cyanotrimethylsilane in the presence of pyridine gave dicyanotrimethylsiloxymethylbenzenes, which were transformed
Preparation of substituted trialkylsilyloxymalonic acid dinitriles
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, (2008/06/13)
A process for the preparation of a substituted trialkylsilyloxymalonic acid dinitrile of the formula STR1 in which R1 is optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted aryl or optionally substituted heteroaryl, R2 is C1-4 -alkyl and n is an integer from 1 to 4, comprising reacting a trialkylsilyl cyanide of the formula with at least one acyl member selected from the group consisting of (a) an acid halide of the formula STR2 in which Hal is fluorine, chlorine, bromine or iodine, (b) an acyl cyanide of the formula STR3 (c) a dimeric acyl cyanide or the formula STR4
