86154-59-8Relevant academic research and scientific papers
REACTION OF HYDROXY AND CARBONYL COMPOUNDS WITH SULFUR TETRAFLUORIDE. IX. REACTIONS OF ALIPHATIC β-DIKETONES WITH SF4
Stepanov, I. V.,Burmakov, A. I.,Kunshenko, B. V.,Alekseeva, L. A.,Yagupol'skii, L. M.
, p. 244 - 248 (2007/10/02)
Aliphatic β-diketones react with sulfur tetrafluoride to form the corresponding di- and tetrafluoro derivatives and also compounds containing double and triple carbon-carbon bonds.In the reactions of 1,1,1-trifluoro derivatives of β-diketones with sulfur tetrafluoride the acyl fluoride is eliminated, and 1,1,1,2-tetrafluoropropene is obtained.Hexafluoroacetylacetone only forms 3-hydroperfluoro-2-pentene under the influence of sulfur tetrafluoride.
