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Intramolecular Catalysis. Part 7. The Smiles Rearrangement of Substituted 2-Hydroxy-2'-nitro- and -2',4'-Dinitro-diphenyl Sulphones, as well as 2-Amino-2',4'-dinitrodiphenyl Sulphide, 2--3-nitropyridine and 2-Hydroxy-2',4'-dinitrodiph
Bowden, Keith,Williams, Philip R.
, p. 215 - 224 (2007/10/02)
Rate coefficients have been measured for the Smiles rearrangement of a series of 4- and 5-substituted 2-hydroxy-2'-nitrodiphenyl sulphones in 70percent (v/v) dioxane-water at 60.0 deg C, and for three substrates at several temperatures.The activation para
