861588-01-4Relevant academic research and scientific papers
(Diacetoxyiodo)benzene-Mediated Reaction of Ethynylcarbinols: Entry to α,α'-Diacetoxy Ketones and Glycerol Derivatives
Liu, Qing-Rong,Pan, Cheng-Xue,Ma, Xiao-Pan,Mo, Dong-Liang,Su, Gui-Fa
, p. 6496 - 6501 (2015)
Efficient access to α,α'-diacetoxy ketones has been developed from ethynylcarbinols and PhI(OAc)2. A plausible mechanism for this was proposed on the basis of experimental studies. The usefulness of α,α'-diacetoxy ketone products has been documented, and glycerol derivatives can be easily synthesized in good yields via a one-pot reaction.
