861676-01-9

Basic information

• Product Name: (2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one
• Synonyms: (2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one
• CAS NO: 861676-01-9
• Molecular Weight: 476.772
• Mol File: 861676-01-9.mol

Chemical Properties

• CAS DataBase Reference: (2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one(861676-01-9)
• EPA Substance Registry System: (2S,4R,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-one(861676-01-9)

Safety Data

• Hazardous Substances Data: 861676-01-9(Hazardous Substances Data)

Upstream product

• 216493-86-6 tert-Butyl-((E)-(1R,2R)-1-ethyl-4-iodo-2-methyl-but-3-enyloxy)-dimethyl-silane 
• 1141775-93-0 tert-butyldimethyl(((3R,4R)-4-methylhex-5-en-3-yl)oxy)silane 
• 1009036-34-3 C₁₇H₂₄O₃ 
• 343782-84-3 (2R,4S)-5-hydroxy-N-methoxy-N,2,4-trimethylpentanamide 
• 74034-73-4 (3R,5S)-3,5-dimethyltetrahydro-2H-pyran-2-one 
• 861675-98-1 (2R,4S)-5-(4-methoxybenzyloxy)-N-methoxy-N,2,4-trimethylpentanamide 
• 861675-99-2 (2R,4S)-5-(4-methoxybenzyloxy)-2,4-dimethylpentanal 
• 861676-00-8 (2S,4R,5R/S,6E,8R,9R)-1-(4-methoxybenzyloxy)-9-(tert-butyldimetylsilyloxy)-2,4,8-trimethylundec-6-en-5-ol 

Relevant articles and documents

Total synthesis of 10-deoxymethynolide and narbonolide

(Chemical Equation Presented) A flexible and convenient approach was developed for the synthesis of 10-deoxymethynolide (1) and narbonolide (2), which are aglycones of the methymycin and the pikromycin families of macrolide antibiotics. These lactones are

Chemoenzymatic synthesis of the polyketide macrolactone 10-deoxymethynolide

The polyketide synthase-derived pikromycin thioesterase (Pik TE) is unique in its ability to catalyze the cyclization of 12- and 14-membered macrolactones. In this investigation, the total synthesis of the natural hexaketide chain elongation intermediate