86177-66-4Relevant academic research and scientific papers
An NMR study of cobalt-catalyzed hydroformylation using para-hydrogen induced polarisation
Godard, Cyril,Duckett, Simon B.,Polas, Stacey,Tooze, Robert,Whitwood, Adrian C.
, p. 2496 - 2509 (2009/12/02)
The syntheses of Co(η3-C3H5)(CO) 2PR2R′ (R, R′ = Ph, Me; R, R′ = Me, Ph; R = R′ = Ph, Cy, CH2Ph) and Co(η3-C 3H5)(CO)(L) (L = dmpe and dppe) are described,
The role of acetyl complexes in the cobalt-catalyzed homologation of methanol
Martin, Jeffrey T.,Baird, Michael C.
, p. 1073 - 1078 (2008/10/08)
It is shown that stoichiometric hydrogenation of MeCOCo(CO)3PMePh2 in methanol yields a product distribution similar to that obtained during the homologation of methanol catalyzed by [Co(CO)3PMePh2]2. The result suggests that the acetyl compound is an intermediate during the catalytic reaction.
