86197-02-6Relevant academic research and scientific papers
Desulfurization of the Epidithiopiperazinedione Sirodesmin PL with Triphenylphosphine: Retention of Configuration at the Bridgehead Carbon Atoms
Ferezou, Jean Pierre,Quesneau-Thierry, Annik,Cesario, Michele,Pascard, Claudine,Barbier, Michel
, p. 5402 - 5406 (2007/10/02)
Sirodesmin PL (3), an epidithiopiperazinedione toxin produced by the fungus Phoma lingam Tode, easily reacts with triphenylphosphine to give the corresponding monosulfide 4.The stereochemical course of the reaction has been studied through chemical transf
