862013-69-2Relevant academic research and scientific papers
Thioether-promoted direct olefination of polyfluoroarenes catalyzed by palladium
Wu, Cai-Zhi,He, Chun-Yang,Huang, Yangen,Zhang, Xingang
supporting information, p. 5266 - 5269 (2013/11/06)
A methyl(phenyl)sulfane-promoted direct olefination of polyfluoroarenes catalyzed by palladium has been reported. With use of this new thioether ligand, a high reaction efficiency and excellent E/Z ratio of desired olefinated polyfluoroarenes were obtained. This represents a first example of thioether promoted oxidative Heck reaction.
Pd(OAc)2 catalyzed olefination of highly electron-deficient perfluoroarenes
Zhang, Xingang,Fan, Shilu,He, Chun-Yang,Wan, Xiaolong,Min, Qiao-Qiao,Yang, Jie,Jiang, Zhong-Xing
supporting information; experimental part, p. 4506 - 4507 (2010/06/12)
An efficient, Pd(OAc)2 catalyzed method for direct olefination of highly electron-deficient perfluoroarenes was developed. The reaction scope includes a series of activated and nonactivated alkenes in moderate to high yields with moderate to high regio- and stereoselectivities.
