86204-05-9

Upstream product

• 600-22-6 pyruvic acid methyl ester 
• 77356-14-0 1,3-dibenzyloxy-2-propanone 

Downstream Products

• 492-30-8 (3S,4S,5R)-3,4-Dihydroxy-5-hydroxymethyl-3-methyl-dihydro-furan-2-one 
• 86204-10-6 3,5-O-dibenzyl-2-C-methyl-DL-lyxonofuranoside 
• 86204-12-8 (3S,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-3-methyl-tetrahydro-furan-2,3-diol 
• 86204-10-6 (2S,3S,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-ethoxy-3-methyl-tetrahydro-furan-3-ol 
• 86204-10-6 (2R,3S,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-ethoxy-3-methyl-tetrahydro-furan-3-ol 
• 86204-09-3 3,5-O-dibenzyl-2-C-methyl-DL-lyxonolactone 

Relevant academic research and scientific papers

SYNTHETIC CONTROL LEADING TO CHIRAL COMPOUNDS

A highly diastereoselective cross aldol reaction is developed using divalent tin enolates formed from stannous trifluoromethanesulfonate and carbonyl compounds.The reaction is extended to a highly enantioselective cross aldol reaction employing chiral dia

DIASTEREOSELECTION IN A DIRECTED CROSSED ALDOL REACTION BETWEEN TWO POLYOXYGENATED KETONES EMPLOYING TIN(II) ENOLATES. A FACILE STEREOSELECTIVE SYNTHESIS OF ETHYL 2-C-METHYL-DL-LYXOFURANOSIDE

Tin(II) enolates of 1,3-dihydroxy-2-propanone derivatives react with a second ketone, methyl pyruvate, under mild conditions to afford the corresponding anti-crossed aldol products in moderate to excellent yields.Facile elaboration to the branched-chain s