86208-59-5

Basic information

• Product Name: 3-trimethylsily;-4,5-dihydro-5-phenylisoxazole
• CAS NO: 86208-59-5
• Molecular Weight: 219.359
• Mol File: 86208-59-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-trimethylsily;-4,5-dihydro-5-phenylisoxazole(CAS DataBase Reference)
• NIST Chemistry Reference: 3-trimethylsily;-4,5-dihydro-5-phenylisoxazole(86208-59-5)
• EPA Substance Registry System: 3-trimethylsily;-4,5-dihydro-5-phenylisoxazole(86208-59-5)

Safety Data

• Hazardous Substances Data: 86208-59-5(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 84405-51-6 Trimethylsilanecarbonitrile oxide 

Downstream Products

• 73627-97-1 3-hydroxy-3-phenylpropanenitrile 
• 14904-40-6 3-phenyl-3-<(trimethylsilyl)oxy>propanenitrile 

Relevant articles and documents

SYNTHESIS AND REARRANGEMENT OF CYCLOADDUCTS FROM TRIMETHYLSILANECARBONITRILE OXIDE

The cycloadducts from trimethylsilanecarbonitrile oxide and ethylenic or acetylenic compounds easily rearrange to open-chain intermediates, which, in turn, are hydrolysed respectively to β-hydroxynitriles and β-oxonitriles.The cycloadducts of the same nitrile oxide with sulfur dioxide and sulfinylamines are unstable, too, leading respectively to trimethylsilylisocyanate and trimethylsilylcarbodiimides.All these reactions are of preparative interest, in comparison with previous methods.