86211-08-7

Upstream product

• 39274-35-6 4-tert-Butyl-thiobenzoesaeure-S-methylester 
• 32508-91-1 1-phenyl-2-decanone 
• 1284948-21-5 C₁₇H₂₆O₂ 
• 1387574-34-6 ethyl 4-(2-oxodecyl)benzoate 
• 1281445-02-0 1-(4-chlorophenyl)-2-decanone 
• 5365-44-6 thiophene-2-carbothioic acid S-methyl ester 
• 1387574-33-5 octyl p-cyanophenylmethyl ketone 
• 5925-72-4 methyl (4-methoxyphenyl)methanethionate 
• 2432-51-1 ethylthioacetic acid methyl ester 
• 13679-61-3 furane-2-monocarboxylic acid S-methylester 
• 1387574-42-6 C₁₂H₁₀OS 
• 1387574-41-5 S-Methyl 3,5-dimethoxybenzothioate 

Downstream Products

• 121782-05-6 ((E)-2-Methylsulfanyl-dec-1-enyl)-cyclohexane 
• 121782-04-5 ((Z)-2-Methylsulfanyl-dec-1-enyl)-cyclohexane 
• 5925-68-8 (S)-methyl thiobenzoate 
• 32508-91-1 1-phenyl-2-decanone 
• 1387574-34-6 ethyl 4-(2-oxodecyl)benzoate 
• 1387574-33-5 octyl p-cyanophenylmethyl ketone 
• 1387574-39-1 4-chlorophenyl nonanate 
• 1281445-02-0 1-(4-chlorophenyl)-2-decanone 
• 121782-03-4 ((E)-3-Methylsulfanyl-undec-2-enyl)-benzene 
• 121782-02-3 ((Z)-3-Methylsulfanyl-undec-2-enyl)-benzene 

Relevant academic research and scientific papers

Rhodium-catalyzed acyl-transfer reaction between benzyl ketones and thioesters: Synthesis of unsymmetric ketones by ketone CO-C bond cleavage and intermolecular rearrangement

In the presence of catalytic amounts of RhH(CO)(PPh3) 3 and 1,2-bis(diphenylphosphino)benzene (dppBz), acyl groups were transferred between benzyl ketones and thioesters/aryl esters. The rhodium complex catalyzed the cleavage of keto