862252-86-6Relevant academic research and scientific papers
Synthesis of α-2-deoxyglycosides by acid-mediated conjugate addition
Mann, Brent,Pitts, Daniel,Koviach, Jennifer
, p. 161 - 168 (2005)
A new method for the synthesis of α-2-deoxyglycosides from hex-1-en-3-uloses is reported. Several acids were surveyed for their ability to mediate the conjugate addition of cyclohexanol to a glucal derived αβ-unsaturated ketone. Although several acids suc
Microwave-assisted stereoselective α-2-deoxyglycosylation of hex-1-en-3-uloses
Lin, Hui-Chang,Wu, Hsu-Hsuan,Lin, Zi-Ping,Lin, Chih-Yuan,Lin, Chun-Hung,Chen, Kun-Lung,Wong, Fung Fuh
supporting information; experimental part, p. 7327 - 7329 (2010/02/28)
α-2-Deoxyglycosides were successfully synthesized by means of microwave-assisted glycosylation. Hex-1-en-3-uloses were treated with a catalytic amount of AlCl3 and various O-nucleophiles including alcohols and sugars under microwave conditions.
