86232-35-1

Upstream product

• 86232-26-0 3-methoxy-2-hydroxy-5-chlorotoluene 
• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 
• 7740-05-8 5-chloro-2-hydroxy-3-methoxy-benzaldehyde 
• 86232-28-2 5-chloro-2,3-dimethoxybenzaldehyde 

Downstream Products

• 86232-37-3 5-chloro-2,3-dimethoxyphenylacetonitrile 
• 86232-47-5 5-chloro-2,3-dihydroxyphenylacetic acid 
• 86232-49-7 methyl 5-chloro-2,3-dihydroxyphenylacetate 
• 86232-39-5 5-chloro-2,3-dimethoxyphenylacetic acid 
• 86232-43-1 methyl 5-chloro-2,3-dimethoxyphenylacetate 
• 86232-45-3 5-chloro-2,3-dimethoxyphenylacetohydroxamic acid 
• 86232-50-0 methyl 2,3-diacetoxy-5-chlorophenylacetate 
• 86232-51-1 2,3-diacetoxy-5-chlorophenylacetic acid 

Relevant academic research and scientific papers

Methanol as hydrogen source: Transfer hydrogenation of aromatic aldehydes with a rhodacycle

A cyclometalated rhodium complex has been shown to perform highly selective and efficient reduction of aldehydes, deriving the hydrogen from methanol. With methanol as both the solvent and hydrogen donor under mild conditions and an open atmosphere, a wide range of aromatic aldehydes were reduced to the corresponding alcohols, without affecting other functional groups.

SYNTHESIS OF 5-HALOGEN-SUBSTITUTED 2,3-DIHYDROXYPHENYLACETIC ACIDS, THEIR ESTERS, AND 2,3-DIMETHOXYPHENYLACETOHYDROXAMIC ACIDS

Many-stage general methods were developed for the synthesis of 5-bromo- or 5-chloro-substituted 2,3-dimethoxyphenylacetic acids from o-vanilin.Methods were also developed for their conversion into the corresponding hydroxamic acids, 2,3-dihydroxyphenylace