862472-07-9Relevant articles and documents
Synthesis of aza-bridged calix(4-methoxy)triazines toward flattened π-conjugated macrocycles
Tanaka, Hiroyuki,Wada, Ayako,Shiro, Motoo,Hioki, Kazuhito,Morisaki, Daiki,Kunishima, Munetaka
, p. 609 - 616 (2009)
Calixtriazines containing a 4-alkoxy-1,3,5-triazine backbone were efficiently synthesized by sequential fragment coupling started from 4-alkoxy-2,6-dichrolo-1,3,5-triazine. These macrocycles tend to form flattened conformations, leading to a stable π-conjugated system, presumably due to the electronic features of the alkoxy-substituent on the triazine rings.