86255-46-1

Upstream product

• 38316-04-0 1-(2-methoxy-phenyl)-2-nitro-ethanol 
• 135-02-4 ortho-anisaldehyde 
• 15241-32-4 1-methoxy-2-(2-nitrovinyl)benzene 

Downstream Products

• 7035-03-2 2-methoxy-benzeneacetonitrile 
• 183657-71-8 C₂₂H₁₈N₂O₅ 
• 59907-33-4 (2-methoxy-phenethyl)-dimethyl-amine 
• 1438253-52-1 (Z)-2-(2-methoxyphenyl)acetaldehyde oxime 
• 82204-36-2 (E)-2-(2-methoxyphenyl)acetaldehyde oxime 
• 183657-32-1 2-(2-Methoxy-phenyl)-1-nitro-ethanone oxime 

Relevant academic research and scientific papers

New approach to oximes through reduction of nitro compounds enabled by visible light photoredox catalysis

A range of nitro compounds are smoothly reduced to their corresponding oximes under the synergistic effects of visible light irradiation, the Ru(bpy)3Cl2 photocatalyst, Hünig's base, Mg(ClO 4)2 activation, and MeCN solvent. This remarkably mild and environmentally benign protocol, when orchestrated with classical Beckmann rearrangement, enables such high-value industrial feedstock as caprolactam to be readily accessed from simple precursor nitrocyclohexane.

The highly chemoselective transfer hydrogenation of the carbon-carbon double bond of conjugated nitroalkenes by a rhodium complex

Chemoselective transfer hydrogenation of conjugated nitroalkenes catalyzed by [RhCl2Cp·]2-diamine complex (Cp ·=η5-C5Me5) using HCOOH/Et3N (5:2) (TEAF) as a hydrogen source was realized. A variety of nitrostyrenes, β-methyl nitrostyrenes, and 3-methyl-4-nitro-5-alkenyl- isoxazoles were reduced smoothly in good to excellent yields in short reaction time. Other functional groups are inert under the reaction conditions.

Visible-light-promoted C-C bond cleavage: Photocatalytic generation of iminium ions and amino radicals

Photoscissors: Structurally variable and synthetically robust iminium ions and amino radicals species could be simultaneously generated by visible-light-promoted photoredox cleavage of the C-C bonds in simple vicinal diamine precursors under very mild reaction conditions. Copyright

Preparation of β-phenylnitroethanes having electron-donating aryl substitution

β-Phenyl-β-hydroxynitroethanes having activating aryl substituents are treated with triethylsilane/trifluoroacetic acid under solventless conditions to give the corresponding phenylnitroethanes. Substrates having no aryl substituents or substituents that

A Highly Chemoselective Reduction of Conjugated Nitro Olefins with Hantzsch Ester in the Presence of Silica Gel

An effective system to reduce conjugated nitro olefins into the corresponding nitroalkanes is described.The system composed Hantzsch ester (HEH) and silica gel in benzene exerts high yield and excellent chemoselectivity under almost neutral conditions.Facile applications of the system to the syntheses of natural products are also described.