862563-48-2Relevant academic research and scientific papers
Asymmetric synthetic access to the hetisine alkaloids: Total synthesis of (+)-nominine
Peese, Kevin M.,Gin, David Y.
supporting information; experimental part, p. 1654 - 1665 (2009/04/04)
A dual cycloaddition strategy for the synthesis of the hetisine alkaloids has been developed, illustrated by a concise asymmetric total synthesis of (+)-nominine (7). The approach relies on an early-stage intramolecular 1,3-dipolar cyclo-addition of a 4-o
Enantioselective approach to the hetisine alkaloids. Synthesis of the 3-methyl-1-aza-tricyclo[5.2.1.03,8]decane core via intramolecular dipolar cycloaddition
Peese, Kevin M.,Gin, David Y.
, p. 3323 - 3325 (2007/10/03)
(Chemical Equation Presented) An efficient, enantioselective approach to the hetisine class of the C20-diterpenoid alkaloids is described. The strategy involves an intramolecular oxidopyridinium dipolar cycloaddition as the key transformation,
