862605-37-6

Basic information

• Product Name: Oxazole, 2,2'-ethylidenebis[4,5-dihydro-4-phenyl-, (4S,4'S)-
• CAS NO: 862605-37-6
• Molecular Formula: C20H20N2O2
• Molecular Weight: 320.391
• Mol File: 862605-37-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Oxazole, 2,2'-ethylidenebis[4,5-dihydro-4-phenyl-, (4S,4'S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxazole, 2,2'-ethylidenebis[4,5-dihydro-4-phenyl-, (4S,4'S)-(862605-37-6)
• EPA Substance Registry System: Oxazole, 2,2'-ethylidenebis[4,5-dihydro-4-phenyl-, (4S,4'S)-(862605-37-6)

Safety Data

• Hazardous Substances Data: 862605-37-6(Hazardous Substances Data)

Upstream product

• 132098-59-0 (S,S)-2,2'-methylenebis(4-phenyl-2-oxazoline) 
• 74-88-4 methyl iodide 
• 20989-17-7 (2S)-2-phenylglycinol 

Downstream Products

• 1415964-15-6 N-(3-aminopropyl)-7,7-bis[(4S)-4,5-dihydro-4-phenyloxazol-2-yl]octanamide 
• 1415964-26-9 C₂₇H₃₂N₂O₄ 

Relevant articles and documents

Bifunctional photocatalysts for enantioselective aerobic oxidation of β-ketoesters

A novel visible-light-responsive chiral ligand has been developed by grafting a triplet state photosensitizer to chiral bisoxazoline ligands. Complexation of this ligand with Ni(acac)2 results in a powerful catalyst for the asymmetric oxidation reaction of β-ketoesters, which uses oxygen or air as the green oxidant and visible light or sunlight as the ideal driving force. Using this protocol, Products containing the α-hydroxy-β-dicarbonyl motif are produced in high yields and with excellent enantiopurities.

Modular synthesis of chiral homo- and heterotrisoxazolines. Improving the enantioselectivity in the asymmetric Michael addition of indole to benzylidene malonate

A simple approach to a diverse set of chiral trisoxazolines is described. Deprotonation of bisoxazolines 2, followed by treatment of 2- chloromethyloxazolines 3, affords chiral trisoxazolines, including chiral homo- and hetero-trisoxazolines in good to hi