862735-85-1

Upstream product

• 101844-21-7 (E)-3-[(dimethyl)phenylsilyl]prop-2-en-1-ol 
• 766-77-8 Dimethylphenylsilane 

Downstream Products

• 862735-96-4 (2R,3R)-3-(dimethyl-phenyl-silanyl)-oxirane-2-carboxylic acid 
• 537033-03-7 (2R,3R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-1-trimethylsilanyloxy-pent-4-en-2-ol 
• 537033-04-8 Acetic acid (2R,3R)-3-(dimethyl-phenyl-silanyl)-2-hydroxy-4-methyl-pent-4-enyl ester 
• 862735-77-1 (Z)-(2R,3R)-3-(dimethyl-phenyl-silanyl)-2-trimethylsilanyloxy-hex-4-enoic acid methyl ester 
• 862735-87-3 (2R,3R)-3-(dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-ynoic acid methyl ester 
• 862735-97-5 (Z)-(2R,3R)-3-(dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-enoic acid methyl ester 
• 862735-86-2 (2R,3R)-3-(dimethyl-phenyl-silanyl)-oxirane-2-carboxylic acid methyl ester 

Relevant academic research and scientific papers

A convenient multigram synthesis of highly enantioenriched methyl 3-silylglycidates

A multigram scale synthesis of the four stereoisomers of methyl 3-silylglycidates (epoxysilanes) with high enantiopurity is described. Key reactions include a Sharpless asymmetric epoxidation (SAE) of a trans-vinylsilane and an enzymatic resolution of a r

Synthesis of a 35-member stereoisomer library of bistramide A: Evaluation of effects on actin state, cell cycle and tumor cell growth

Synthesis and preliminary biological evaluation of a 35-member library of bistramide A stereoisomers are reported. All eight stereoisomers of the C1-C13 tetrahydropyran fragment of the molecule were prepared utilizing crotylsilane reagents 9 and 10 in our