862771-84-4Relevant academic research and scientific papers
Iron(II)- and cobalt(II) complexes with tridentate bis(imino)pyridine nitrogen ligands bearing chiral bulky aliphatic and aromatic substituents: Crystal structure of [CoCl2{2,6-bis[R-(+)-(bornylimino)methyl] pyridine}]
Lappalainen, Kristian,Yliheikkilae, Katariina,Abu-Surrah, Adnan S.,Polamo, Mika,Leskelae, Markku,Repo, Timo
, p. 763 - 768 (2005)
Iron(II) and cobalt(II) complexes (7-15) based on new aldimine 2,6-bis[(imino)methyl]pyridine (1,2,4,6) and ketimine (2,6-bis[(imino)ethyl] pyridine (3,5) ligands with bulky chiral aliphatic or aromatic terminal groups have been prepared and characterized by 1H NMR, 13C NMR, IR-, mass spectroscopy (EI), and elemental analysis. The complex [CoCl 2(BBoMP)]·1/2 CHCl3 (13) (BBoMP: 2,6-bis{(R-(+)-(bornylimino)-methyl}pyridine) crystallizes in monoclinic space group P21 with cell dimensions: a = 7.6603(11) A, b = 28.3153(14) A, c = 13.537(2) A, V = 2908.1(6) A3, Z = 4. The coordination sphere around Co is distorted trigonal bipyramidal.
