862772-15-4Relevant academic research and scientific papers
Diferrocenylcyclopropenyl cations. Synthesis, structures, and some chemical properties
Klimova, Elena I.,Berestneva, Tatiana Klimova,Ortega, Simon Hernández,Iturbide, Daniel Méndez,Marquez, Alfonso García,García, Marcos Martínez
, p. 3333 - 3339 (2005)
Synthesis of diferrocenylcyclopropenyl tetrafluoroborates with hetero-substituents in the three-membered ring, viz., ethoxy, trityloxy, ferrocenyl(phenyl)methoxy, N,N-diethylamino, piperidino, and morpholino, is described. The spatial structure of diferrocenyl(morpholino)cyclopropenyl tetrafluoroborate was established based on the data from X-ray diffraction analysis. Under the action of potassium tert-butoxide, all the diferrocenylcyclopropenyl tetrafluoroborates undergo three-membered ring-opening with formation of the corresponding 2,3-diferrocenylacrylic acid derivatives. A mechanism of the ring-opening is suggested.
