86294-78-2

Basic information

• Product Name: Silane, trimethyl[[(1E)-1-phenoxy-1-propenyl]oxy]-
• CAS NO: 86294-78-2
• Molecular Formula: C12H18O2Si
• Molecular Weight: 222.359
• Mol File: 86294-78-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[[(1E)-1-phenoxy-1-propenyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[[(1E)-1-phenoxy-1-propenyl]oxy]-(86294-78-2)
• EPA Substance Registry System: Silane, trimethyl[[(1E)-1-phenoxy-1-propenyl]oxy]-(86294-78-2)

Safety Data

• Hazardous Substances Data: 86294-78-2(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 637-27-4 phenyl propionate 

Downstream Products

• 1138247-16-1 phenyl 2-(trifluoromethyl)propionate 
• 144408-64-0 anti-phenyl 3-hydroxy-2-methyl-hexanoate 
• 144408-65-1 (2S,3R)-3-Hydroxy-2-methyl-hexanoic acid phenyl ester 
• 215536-74-6 2-Methyl-5-phenyl-3-[N'-(4-trifluoromethyl-benzoyl)-hydrazino]-pentanoic acid phenyl ester 
• 136312-69-1 phenyl erythro-3-hydroxy-2-methyl-3-phenylpropanoate 

Relevant articles and documents

Total Synthesis of Leiodermatolide A via Transfer Hydrogenative Allylation, Crotylation, and Propargylation: Polyketide Construction beyond Discrete Allyl- or Allenylmetal Reagents

The total synthesis of leiodermatolide A was accomplished in 13 steps (LLS). Transfer hydrogenative variants of three carbonyl additions that traditionally rely on premetalated reagents (allylation, crotylation, and propargylation) are deployed together i